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Acetone peroxide : ウィキペディア英語版
Acetone peroxide

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Acetone peroxide (triacetone triperoxide, peroxyacetone, TATP, TCAP) is an organic peroxide and a primary high explosive. It takes the form of a white crystalline powder with a distinctive bleach-like odor.
It is susceptible to heat, friction and shock. The instability is greatly altered by impurities, including its own oligomers. It is not easily soluble in water.
== History ==

Acetone peroxide was discovered in 1895 by Richard Wolffenstein.〔Wolffenstein, Richard (1895) Deutsches Reich Patent 84,953.〕 He was the first chemist to use inorganic acids as catalysts. He was also the first researcher to receive a patent for using the peroxide as an explosive compound. In 1900 Bayer and Villiger described in the same journal the first synthesis of the dimer and also described use of acids for the synthesis of both peroxides.〔; See also 〕 Information about these procedures including the relative proportions of monomer, dimer, and trimer is also available in an article by Milas and Golubović. Other sources include details of crystal structure and 3D analysis - see ''The Chemistry of Peroxides'' edited by Saul Patai (pp. 396–7), as well as the ''Textbook of Practical Organic Chemistry'' by Vogel.

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